[Di-n-butytin tridentate acylhydrazone Schiff base complexes: synthesis and studies by infrared spectroscopy].

ABSTRACT

Four tridentate acylhydrazone schiff base ligands H2L [H2L1C6H5C(O)NHN = CHC6H4OH-2, H2L2C6H5C(O)NHN = CHC6H3(OH)(2)-2,4, H2L3NC5H4C(O)NHN = CHC6H4OH-2, H2L4NC5H4C(O)NHN = CHC6H3(OH)(2)-2,4] were synthesized and use to form four novel di-n-Butytin complexes of the type (n-Bu)2SnL with di-n-Butytin oxide [(n-Bu)2SnO]. All these ligands and complexes were characterized by elemental analysis and infrared spectroscopy. Their principal infrared spectral absorption peaks were assigned and discussed for the region of 4,000-400 cm-1. A comparison of the infrared spectra of the ligands with those of the corresponding complexes reveals that the disappearance of the bands assigned to carbonyl unambiguously confirms that the ligands coordinate with tin in the enol form. The coordination manner for tridentate acylhydrazone schiff base ligands with tin atom in the complexes was determined. The results indicated that the Sn atom in these complexes is five-coordinated.