Thickness and density profiles of polyelectrolyte brushes: dependence on grafting density and salt concentration.

ABSTRACT

We have performed neutron reflectivity measurements on a monolayer of charged diblock copolymers in a Langmuir trough, and determined precise density profiles of the polyelectrolyte brush at different densities. We obtain profiles in good agreement with existing self-consistent field computations, both for the osmotic and the salted brush regime. We show that the osmotic brush's thickness increases with density.