A phosphine-catalyzed [3+6] annulation reaction of modified allylic compounds and tropone.
Org Lett
; 7(10): 1987-9, 2005 May 12.
Article
em En
| MEDLINE
| ID: mdl-15876036
ABSTRACT
A novel phosphine-catalyzed reaction of modified allylic compounds, including acetates, bromides, chlorides, or tert-butyl carbonates derived from the Morita-Baylis-Hillman (MBH) reaction with tropone to yield [3+6] annulation products in excellent yields was developed. It offers a simple and convenient method for constructing bridged nine-membered carbocycles.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Org Lett
Assunto da revista:
BIOQUIMICA
Ano de publicação:
2005
Tipo de documento:
Article