Copper-catalyzed olefin aminoacetoxylation.
Org Lett
; 12(18): 4110-3, 2010 Sep 17.
Article
em En
| MEDLINE
| ID: mdl-20735066
ABSTRACT
A new catalyst system for intramolecular olefin aminoacetoxylation is described. In contrast to previously reported palladium- and copper-catalyzed systems, the conditions outlined in this communication favor piperdine formation with terminal olefin substrates and induce cyclization with traditionally less reactive disubstituted olefins.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Acetona
/
Cobre
/
Alcenos
/
Aminas
Idioma:
En
Revista:
Org Lett
Assunto da revista:
BIOQUIMICA
Ano de publicação:
2010
Tipo de documento:
Article
País de afiliação:
Estados Unidos