Description of the nanostructured morphology of [6,6]-phenyl-C61 -butyric acid methyl ester (PCBM) by XRD, DSC and solid-state NMR.
Magn Reson Chem
; 49(5): 242-7, 2011 May.
Article
em En
| MEDLINE
| ID: mdl-21491481
ABSTRACT
PCBM or [6,6]-phenyl-C(61)-butyric acid methyl ester is nowadays still one of the most successful electron acceptors for plastic bulk heterojunction (BHJ) photovoltaic devices. In this study, a set of complementary techniques, i.e. solid-state NMR, XRD and DSC, is proposed as a fast and sensitive tool to screen the morphology of PCBM specimens with different preparation histories. Based on proton NMR relaxation decay time values, an interval can be derived that situates the average crystal dimensions and which can further be refined on the basis of XRD patterns and DSC thermograms.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Magn Reson Chem
Assunto da revista:
QUIMICA
Ano de publicação:
2011
Tipo de documento:
Article
País de afiliação:
Bélgica