Palladium urchin-like nanostructures and their H2 sorption properties.

ABSTRACT

Urchin-like palladium nanostructures were synthesized by slow radiolytic reduction of Pd(II) in cetylpyridinium chloride (CPCl) micellar solution. They were formed by polycrystalline nanowires originating from the same core. The growth process leading to these urchin-like structures has been studied. These three-dimensional (3D) nanostructures were obtained at high Pd concentration (0.1 M) which led to a relatively large quantity of nanomaterials. These nanostructures show very interesting cycling sorption properties for hydrogen storage.