Convergent synthesis of the tetrasaccharide repeating unit of the O-antigen of Shigella boydii type 9.
Beilstein J Org Chem
; 7: 1182-8, 2011.
Article
em En
| MEDLINE
| ID: mdl-21977201
ABSTRACT
A convenient synthesis of the tetrasaccharide repeating unit of the O-antigen of Shigella boydii type 9 has been achieved in excellent yield using a [2 + 2] block glycosylation strategy. TEMPO-mediated selective oxidation of the primary alcohol of the tetrasaccharide derivative 8 to the carboxylic group followed by deprotection of the functional groups furnished target tetrasaccharide 1 as its 4-methoxyphenyl glycoside in high yield.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Beilstein J Org Chem
Ano de publicação:
2011
Tipo de documento:
Article