Ferric perchlorate-mediated synthesis of 1,2-fullerenols C60(OCOR)(OH).

Li, Fa-Bao; You, Xun; Wang, Guan-Wu

Li, Fa-Bao; You, Xun; Wang, Guan-Wu.

Afiliação

Li FB; CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.

J Org Chem ; 77(15): 6643-7, 2012 Aug 03.

Article em En | MEDLINE | ID: mdl-22804566

ABSTRACT

ABSTRACT

1,2-Fullerenols C(60)(OCOR)(OH) have been facilely synthesized via the one-step reaction of [60]fullerene with acid chlorides promoted by ferric perchlorate. A possible reaction mechanism for the product formation is proposed.

Assuntos

Compostos Férricos/química; Fulerenos/química; Percloratos/química; Estrutura Molecular

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Compostos Férricos / Percloratos / Fulerenos Idioma: En Revista: J Org Chem Ano de publicação: 2012 Tipo de documento: Article

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