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cis-Diamminedichloridoplatinum(II) N,N-dimethyl-formamide monosolvate.
Johnston, Dean H; Miller, Nathanael A; Tackett, Cory B.
Afiliação
  • Johnston DH; Department of Chemistry, Otterbein University, Westerville, OH 43081, USA. djohnston@otterbein.edu
Acta Crystallogr Sect E Struct Rep Online ; 68(Pt 7): m863-4, 2012 Jul 01.
Article em En | MEDLINE | ID: mdl-22807714
In the title compound, cis-[PtCl2(NH3)2]·C3H7NO, the metal complex mol-ecules are stacked parallel to the b axis, forming close Pt⋯Pt inter-actions of 3.4071 (7) and 3.5534 (8) Šand weak N-H⋯Cl hydrogen bonds between the ammine ligand and the Cl atoms of the neighboring complex. Conventional N-H⋯O hydrogen bonds are formed between ammine ligands and the O atom of adjacent N,N-dimethyl-formamide mol-ecules. The crystal was found to be a split crystal and was analyzed using two domains related by a rotation of ca 4.4° about the reciprocal axis (-0.351 1.000 0.742) and refined to give a minor component fraction of 0.084 (6).

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Ano de publicação: 2012 Tipo de documento: Article País de afiliação: Estados Unidos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Ano de publicação: 2012 Tipo de documento: Article País de afiliação: Estados Unidos