Ring-opening polymerization of cyclic esters with lithium amine-bis(phenolate) complexes.
Dalton Trans
; 42(10): 3504-20, 2013 Mar 14.
Article
em En
| MEDLINE
| ID: mdl-23280340
Lithium compounds of tetradentate amino-bis(phenolato)-tetrahydrofuranyl ligands, Li(2)[L1] (1) and Li(2)[L2] (2) (where [L1] = 2-tetrahydrofuranyl-N,N-bis(2-methylene-4-methyl-6-tert-butylphenolate), and [L2] = 2-tetrahydrofuranyl-N,N-bis(2-methylene-4,6-tert-butylphenolate)) were characterized by multinuclear solution NMR and solid-state (6)Li and (7)Li NMR spectroscopy. The proligands, n-propylamino-N,N-bis(2-methylene-4-methyl-6-tert-butylphenol), (H(2)[L3]) and benzylamino-N,N-bis(2-methylene-4,6-di-tert-amylphenol), H(2)[L4] were reacted with n-butyllithium in THF to give the related dilithium compounds Li(2)[L3] (4) and Li(2)[L4] (5), respectively. The pyridine adduct of 1, (py)(2)Li(2)[L1] (3) and complexes 4 and 5 have been structurally characterized by single-crystal X-ray diffraction and NMR spectroscopy. The reactivity of these complexes for the ring-opening polymerization of rac-lactide, as well as the influences of monomer concentration, monomer/Li molar ratio, polymerization temperature and time, were studied.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
Canadá