Elastic electron scattering from water vapor and ice at high momentum transfer.
J Chem Phys
; 138(4): 044307, 2013 Jan 28.
Article
em En
| MEDLINE
| ID: mdl-23387584
ABSTRACT
We compare the area, peak separation, and width of the H and O elastic peak for light and heavy water, as observed in spectra of keV electrons scattered over large angles. Peak separation is well reproduced by the theory, but the OH area ratio is somewhat larger than expected and is equal to the OD area ratio. Thus no anomalous scattering from H was observed. Only minor differences are observed for scattering from a gaseous or a solid target. The extracted mean kinetic energy of H and D agreed within 5% with the calculated ones for ice. For the more difficult vapor measurements agreement was on a 12% level. A preliminary attempt to extract the O kinetic energy in ice agreed within 10% with the calculated values.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Vapor
/
Elasticidade
/
Elétrons
/
Gelo
Idioma:
En
Revista:
J Chem Phys
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
Austrália