A method for synthesis of homoallylic bromide.

Qi, Wenke; Wang, Peipei; Fan, Liyuan; Zhang, Songlin

Qi, Wenke; Wang, Peipei; Fan, Liyuan; Zhang, Songlin.

Afiliação

Qi W; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Dushu Lake Campus, Soochow University, Suzhou 215123, People's Republic of China.

J Org Chem ; 78(12): 5918-24, 2013 Jun 21.

Article em En | MEDLINE | ID: mdl-23688038

ABSTRACT

ABSTRACT

Cyclopropyl Grignard reagents react with carbonyl compounds in the presence of diethyl phosphite to give homoallylic bromides. The reaction is effectively carried out under mild conditions in a one-pot fashion with moderate to good yields.

Assuntos

Compostos Alílicos/síntese química; Bromo/química; Fosfitos/química; Benzofenonas/química; Catálise; Estrutura Molecular

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Bromo / Fosfitos / Compostos Alílicos Idioma: En Revista: J Org Chem Ano de publicação: 2013 Tipo de documento: Article

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