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Synthesis and reactivity of new aminophenolate complexes of nickel.
Yu, Siqi; Wang, Huan; Sledziewski, Jill E; Madhira, Venkata N; Takahashi, Cyrus G; Leon, Michelle K; Dudkina, Yulia B; Budnikova, Yulia H; Vicic, David A.
Afiliação
  • Yu S; Department of Chemistry, Lehigh University, 6 E. Packer Ave., Bethlehem, PA 18015, USA. siy212@lehigh.edu.
  • Wang H; Department of Chemistry, Lehigh University, 6 E. Packer Ave., Bethlehem, PA 18015, USA. sanni.wangh@gmail.com.
  • Sledziewski JE; Department of Chemistry, Lehigh University, 6 E. Packer Ave., Bethlehem, PA 18015, USA. jillsledz@yahoo.com.
  • Madhira VN; Department of Chemistry, University of Hawaii, 2545 McCarthy Mall, Honolulu, HI 96822, USA. sharma.madhira@gmail.com.
  • Takahashi CG; Department of Chemistry, University of Hawaii, 2545 McCarthy Mall, Honolulu, HI 96822, USA. cyrus.takahashi@gmail.com.
  • Leon MK; Department of Chemistry, Lehigh University, 6 E. Packer Ave., Bethlehem, PA 18015, USA. mkl215@lehigh.edu.
  • Dudkina YB; Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, 8 Arbuzov str., Kazan 420088, Russia. dudkina.yu@gmail.com.
  • Budnikova YH; Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, 8 Arbuzov str., Kazan 420088, Russia. yulia@iopc.ru.
  • Vicic DA; Department of Chemistry, Lehigh University, 6 E. Packer Ave., Bethlehem, PA 18015, USA. dav512@lehigh.edu.
Molecules ; 19(9): 13603-13, 2014 Sep 02.
Article em En | MEDLINE | ID: mdl-25185067
New well-defined, paramagnetic nickel complexes have been prepared and characterized by X-ray crystallography. The complexes were found to be active for the cross-coupling of alkyl electrophiles (especially ethyl 2-bromobutyrate) with alkyl Grignard reagents. The ligand architecture in these new complexes could potentially be rendered chiral, opening up future possibilities for performing asymmetric cross-coupling reactions.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Complexos de Coordenação / Aminofenóis / Níquel Idioma: En Revista: Molecules Assunto da revista: BIOLOGIA Ano de publicação: 2014 Tipo de documento: Article País de afiliação: Estados Unidos
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Complexos de Coordenação / Aminofenóis / Níquel Idioma: En Revista: Molecules Assunto da revista: BIOLOGIA Ano de publicação: 2014 Tipo de documento: Article País de afiliação: Estados Unidos