Communication: Direct tests of single-parameter aging.
J Chem Phys
; 142(24): 241103, 2015 Jun 28.
Article
em En
| MEDLINE
| ID: mdl-26133403
This paper presents accurate data for the physical aging of organic glasses just below the glass transition probed by monitoring the following quantities after temperature up and down jumps: the shear-mechanical resonance frequency (â¼360 kHz), the dielectric loss at 1 Hz, the real part of the dielectric constant at 10 kHz, and the loss-peak frequency of the dielectric beta process (â¼10 kHz). The setup used allows for keeping temperature constant within 100 µK and for thermal equilibration within a few seconds after a temperature jump. The data conform to a new simplified version of the classical Tool-Narayanaswamy aging formalism, which makes it possible to calculate one relaxation curve directly from another without any fitting to analytical functions.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
J Chem Phys
Ano de publicação:
2015
Tipo de documento:
Article
País de afiliação:
Dinamarca