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Controlled aqueous polymerization of acrylamides and acrylates and "in situ" depolymerization in the presence of dissolved CO2.
Lloyd, Danielle J; Nikolaou, Vasiliki; Collins, Jennifer; Waldron, Christopher; Anastasaki, Athina; Bassett, Simon P; Howdle, Steven M; Blanazs, Adam; Wilson, Paul; Kempe, Kristian; Haddleton, David M.
Afiliação
  • Lloyd DJ; Department of Chemistry, University of Warwick, CV4 7AL Gibbet Hill, West Midlands, UK. D.M.Haddleton@warwick.ac.uk.
  • Nikolaou V; Department of Chemistry, University of Warwick, CV4 7AL Gibbet Hill, West Midlands, UK. D.M.Haddleton@warwick.ac.uk.
  • Collins J; Department of Chemistry, University of Warwick, CV4 7AL Gibbet Hill, West Midlands, UK. D.M.Haddleton@warwick.ac.uk.
  • Waldron C; Department of Chemistry, University of Warwick, CV4 7AL Gibbet Hill, West Midlands, UK. D.M.Haddleton@warwick.ac.uk.
  • Anastasaki A; Department of Chemistry, University of Warwick, CV4 7AL Gibbet Hill, West Midlands, UK. D.M.Haddleton@warwick.ac.uk and Monash Institute of Pharmaceutical Sciences, Monash University, Parkville, VIC 3052, Australia.
  • Bassett SP; School of Chemistry, University of Nottingham, Nottingham, NG7 2RD, UK.
  • Howdle SM; School of Chemistry, University of Nottingham, Nottingham, NG7 2RD, UK.
  • Blanazs A; BASF SE, 67065, Ludwigshafen, Germany.
  • Wilson P; Department of Chemistry, University of Warwick, CV4 7AL Gibbet Hill, West Midlands, UK. D.M.Haddleton@warwick.ac.uk and Monash Institute of Pharmaceutical Sciences, Monash University, Parkville, VIC 3052, Australia.
  • Kempe K; Department of Chemistry, University of Warwick, CV4 7AL Gibbet Hill, West Midlands, UK. D.M.Haddleton@warwick.ac.uk and Monash Institute of Pharmaceutical Sciences, Monash University, Parkville, VIC 3052, Australia.
  • Haddleton DM; Department of Chemistry, University of Warwick, CV4 7AL Gibbet Hill, West Midlands, UK. D.M.Haddleton@warwick.ac.uk and Monash Institute of Pharmaceutical Sciences, Monash University, Parkville, VIC 3052, Australia.
Chem Commun (Camb) ; 52(39): 6533-6, 2016 May 05.
Article em En | MEDLINE | ID: mdl-27111827
ABSTRACT
Aqueous copper-mediated radical polymerization of acrylamides and acrylates in carbonated water resulted in high monomer conversions (t < 10 min) before undergoing depolymerization (60 min > t > 10 min). The regenerated monomer was characterized and repolymerized following deoxygenation of the resulting solutions to reyield polymers in high conversions that exhibit low dispersities.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Acrilamidas / Acrilatos / Resinas Acrílicas / Dióxido de Carbono Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2016 Tipo de documento: Article País de afiliação: Reino Unido
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Acrilamidas / Acrilatos / Resinas Acrílicas / Dióxido de Carbono Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2016 Tipo de documento: Article País de afiliação: Reino Unido