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Visible-Light Induced Direct Synthesis of Polysubstituted Furans from Cyclopropyl Ketones.
Feng, Liyan; Yan, Hang; Yang, Chao; Chen, Dafa; Xia, Wujiong.
Afiliação
  • Feng L; State Key Lab of Urban Water Resource and Environment, Shenzhen Graduate School, Harbin Institute of Technology , Harbin 150080 China.
  • Yan H; State Key Lab of Urban Water Resource and Environment, Shenzhen Graduate School, Harbin Institute of Technology , Harbin 150080 China.
  • Yang C; State Key Lab of Urban Water Resource and Environment, Shenzhen Graduate School, Harbin Institute of Technology , Harbin 150080 China.
  • Chen D; State Key Lab of Urban Water Resource and Environment, Shenzhen Graduate School, Harbin Institute of Technology , Harbin 150080 China.
  • Xia W; State Key Lab of Urban Water Resource and Environment, Shenzhen Graduate School, Harbin Institute of Technology , Harbin 150080 China.
J Org Chem ; 81(16): 7008-22, 2016 08 19.
Article em En | MEDLINE | ID: mdl-27167091
ABSTRACT
In this article, a photoredox protocol for the synthesis of furans via oxidative coupling of olefin generated in situ from cyclopropyl ketones with ketonic oxygen atom is presented. Moreover, bromination of furans in the presence of overstoichiometric oxidant has been achieved with high regioselectivity.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2016 Tipo de documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2016 Tipo de documento: Article