Visible Light-Induced Radical Rearrangement to Construct C-C Bonds via an Intramolecular Aryl Migration/Desulfonylation Process.

Li, Yuyuan; Hu, Bei; Dong, Wuheng; Xie, Xiaomin; Wan, Jun; Zhang, Zhaoguo

Li, Yuyuan; Hu, Bei; Dong, Wuheng; Xie, Xiaomin; Wan, Jun; Zhang, Zhaoguo.

Afiliação

Li Y; Key Laboratory of Sensor Analysis of Tumor Marker, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology , Qingdao 266042, China.
Hu B; School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University , 800 Dongchuan Road, Shanghai, 200240, China.
Dong W; School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University , 800 Dongchuan Road, Shanghai, 200240, China.
Xie X; School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University , 800 Dongchuan Road, Shanghai, 200240, China.
Wan J; Key Laboratory of Sensor Analysis of Tumor Marker, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology , Qingdao 266042, China.
Zhang Z; School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University , 800 Dongchuan Road, Shanghai, 200240, China.

J Org Chem ; 81(16): 7036-41, 2016 08 19.

Article em En | MEDLINE | ID: mdl-27351977

ABSTRACT

ABSTRACT

A highly efficient intramolecular selective aryl migration/desulfonylation of 2-bromo-N-aryl-N-(arenesulfonyl)amide via visible light-induced photoredox catalysis has been accomplished. This approach allows for the construction of a variety of multisubstituted N,2-diarylacetamide under mild reaction conditions.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2016 Tipo de documento: Article País de afiliação: China

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