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[Mn(III)Mn(IV)2Mo14O56](17-): A Mixed-Valence Meso-Polyoxometalate Anion Encapsulated by a 64-Nuclearity Silver Cluster.
Wang, Jian-Yu; Liu, Kuan-Guan; Guan, Zong-Jie; Nan, Zi-Ang; Lin, Yu-Mei; Wang, Quan-Ming.
Afiliação
  • Wang JY; Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
  • Liu KG; Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
  • Guan ZJ; Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
  • Nan ZA; Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
  • Lin YM; Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
  • Wang QM; Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
Inorg Chem ; 55(14): 6833-5, 2016 Jul 18.
Article em En | MEDLINE | ID: mdl-27362281
A 64-nuclearity silver cluster encapsulating a unique POM anion [Mn(III)Mn(IV)2Mo14O56](17-) has been synthesized. The formation of the templating core performs a reassembly process for increasing nuclearities from {MnMo9} to {Mn3Mo14}. It represents a rare inorganic meso anion containing mixed-valent Mn that is built up by d-{Mn(IV)Mo7} and l-{Mn(IV)Mo7} units connecting together through a {Mn(III)} fragment.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2016 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2016 Tipo de documento: Article