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Palladium-Catalyzed Decarboxylative Synthesis of Arylamines.
Dai, Qipu; Li, Peihe; Ma, Nuannuan; Hu, Changwen.
Afiliação
  • Dai Q; Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology , Beijing 100081, People's Republic of China.
  • Li P; Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology , Beijing 100081, People's Republic of China.
  • Ma N; Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology , Beijing 100081, People's Republic of China.
  • Hu C; Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology , Beijing 100081, People's Republic of China.
Org Lett ; 18(21): 5560-5563, 2016 11 04.
Article em En | MEDLINE | ID: mdl-27754691
ABSTRACT
A novel approach has been developed for the synthesis of arylamines via the palladium-catalyzed intramolecular decarboxylative coupling (IDC) of aroyloxycarbamates, obtained in situ by reacting aryl carboxylic acids with hydroxycarbamates. The reaction offers facile access to structurally diverse arylamines with the site-specific formation of the C(sp2)-N bond under mild conditions.
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Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2016 Tipo de documento: Article
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Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2016 Tipo de documento: Article