Quest for the Ncb-type Metal-Organic Framework Platform: A Bifunctional Ligand Approach Meets Net Topology Needs.
Inorg Chem
; 56(13): 7328-7331, 2017 Jul 03.
Article
em En
| MEDLINE
| ID: mdl-28613856
ABSTRACT
A custom-designed bifunctional ligand was used to connect an in situ formed Co3(OH) cluster affording a porous metal-organic framework, which represents the first case of ncb-type networks constructed from a single kind of ditopic ligand. Noticeably, the activated MOF shows high volumetric C2H2 uptake and excellent adsorption selectivity for C2H2/CO2 separation at room temperature with a low sorption heat.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2017
Tipo de documento:
Article