Interfering resonance as an underlying mechanism in the adaptive feedback control of radiationless transitions: Retinal isomerization.
J Chem Phys
; 147(11): 114107, 2017 Sep 21.
Article
em En
| MEDLINE
| ID: mdl-28938828
ABSTRACT
Control of molecular processes via adaptive feedback often yields highly structured laser pulses that have eluded physical explanation. By contrast, coherent control approaches propose physically transparent mechanisms but are not readily visible in experimental results. Here, an analysis of a condensed phase adaptive feedback control experiment on retinal isomerization shows that it manifests a quantum interference based coherent control mechanism control via interfering resonances. The result promises deep insight into the physical basis for the adaptive feedback control of a broad class of bound state processes.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Chem Phys
Ano de publicação:
2017
Tipo de documento:
Article
País de afiliação:
Canadá