C(sp2)-H functionalization of aldehyde-derived hydrazones via a radical process.
Org Biomol Chem
; 16(8): 1227-1241, 2018 02 21.
Article
em En
| MEDLINE
| ID: mdl-29431815
ABSTRACT
This review is focused on the recent advances in the C(sp2)-H functionalization of aldehyde-derived hydrazones via a radical process. Diverse substituted hydrazones including N-heterocycles are afforded under mild conditions with excellent selectivities. In general, an aminyl radical as the key intermediate is involved during the reaction process, and a broad reaction scope with good functional group tolerance can be observed. In some cases, a photocatalyst under visible light irradiation is involved, which initiates the radical reaction.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Org Biomol Chem
Assunto da revista:
BIOQUIMICA
/
QUIMICA
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
China