Electron-Catalyzed Coupling of Magnesium Amides with Aryl Iodides.

Kiriyama, Kazuya; Okura, Keisho; Tamakuni, Fumiko; Shirakawa, Eiji

Kiriyama, Kazuya; Okura, Keisho; Tamakuni, Fumiko; Shirakawa, Eiji.

Afiliação

Kiriyama K; Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, Japan.
Okura K; Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, Japan.
Tamakuni F; Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, Japan.
Shirakawa E; Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo, 669-1337, Japan.

Chemistry ; 24(18): 4519-4522, 2018 Mar 26.

Article em En | MEDLINE | ID: mdl-29450924

ABSTRACT

ABSTRACT

An electron was found to catalyze the coupling of magnesium diarylamides with aryl iodides giving triarylamines through a radical-anion intermediate. The transformation requires no transition metal catalysts or additives, and a wide array of products are formed in good-to-excellent yields.

Palavras-chave

C−N coupling; organic transformations; radical-anions; single-electron transfer; triarylamines

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Japão

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