Transition-Metal-Free C-P Bond Formation via Decarboxylative Phosphorylation of Cinnamic Acids with P(O)H Compounds.

Liu, Lixin; Zhou, Dan; Dong, Jianyu; Zhou, Yongbo; Yin, Shuang-Feng; Han, Li-Biao

Liu, Lixin; Zhou, Dan; Dong, Jianyu; Zhou, Yongbo; Yin, Shuang-Feng; Han, Li-Biao.

Afiliação

Liu L; State Key Laboratory of Chemo/Biosensing and Chemometrics , College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082 , China.
Zhou D; State Key Laboratory of Chemo/Biosensing and Chemometrics , College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082 , China.
Dong J; State Key Laboratory of Chemo/Biosensing and Chemometrics , College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082 , China.
Zhou Y; State Key Laboratory of Chemo/Biosensing and Chemometrics , College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082 , China.
Yin SF; State Key Laboratory of Chemo/Biosensing and Chemometrics , College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082 , China.
Han LB; National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba , Ibaraki 305-8565 , Japan.

J Org Chem ; 83(7): 4190-4196, 2018 04 06.

Article em En | MEDLINE | ID: mdl-29498279

ABSTRACT

ABSTRACT

A novel, transition-metal-free phosphorylation of cinnamic acids with P(O)H compounds has been developed via radical-promoted decarboxylation under mild conditions. This method provides simple, efficient, and versatile access to valuable ( E)-alkenylphosphine oxides in satisfactory yields with a wide variety of substrates.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2018 Tipo de documento: Article País de afiliação: China

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