Cyclic Anion-Responsive π-Electronic Molecules That Overcome Energy Losses Induced by Conformation Changes.
Org Lett
; 20(11): 3268-3272, 2018 06 01.
Article
em En
| MEDLINE
| ID: mdl-29790757
ABSTRACT
Preorganized structures suitable for anion binding were prepared by introducing dipyrrolyldiketone BF2 complexes as acyclic anion-responsive π-electronic molecules into macrocycles. Pyrrole-inverted conformations, which typically present low stability in the case of acyclic derivatives, were obtained by covalent linkages through ring-closing olefin metathesis, exhibiting extremely high affinity for different anions.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Org Lett
Assunto da revista:
BIOQUIMICA
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
Japão