Metal bis(acetylide) complex molecular wires: concepts and design strategies.
Dalton Trans
; 47(40): 14125-14138, 2018 Oct 16.
Article
em En
| MEDLINE
| ID: mdl-29951669
ABSTRACT
The past decade has seen a remarkable surge in studies of thin-film and single-molecule electronics, due in no small part to the development and advancement of experimental methods for the construction and measurement of metal|molecule|metal junctions. Within the plethora of molecular structures that have been investigated, metal complexes of general form trans-M(C[triple bond, length as m-dash]CR)2(Ln) have attracted attention from the inorganic and organometallic chemistry community in the search for efficient molecular wires due to the potential π-d-π orbital mixing along the molecular backbone. In this article progress towards this goal will be summarised, and design strategies for future molecular components discussed.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
Reino Unido