Weakening the Aggregations of Polymer Chains toward Efficient Non-Fullerene Polymer Solar Cells.
Macromol Rapid Commun
; 39(21): e1800446, 2018 Nov.
Article
em En
| MEDLINE
| ID: mdl-30144192
ABSTRACT
The 2D asymmetric benzodithiophene (BDT) unit is used as a donor unit to construct one new polymer PBDTBDD-Th with benzo[1,2-c4,5-c']dithiophene-4,8-dione (BDD) as acceptor building block. In comparison to the polymer PBDTsTh-BDD with a side chain containing a sulfur atom, the devices based on PBDTBDD-Th/ITIC show better performance due to the introduction of carbon atoms in the side chain, which could weaken the self-aggregations of polymer chains. As a result, the devices based on PBDTBDD-Th/ITIC blends yield power conversion efficiencies (PCEs) over 10%, much higher than those based on PBDTsTh-BDD/ITIC blends (7.09%). The exciton dissociation probabilities (P diss ) of a device based on PBDTBDD-Th/ITIC blends is 95.3%, which suggests that the device achieves good exciton dissociation and charge transfer. In general, the polymer PBDTBDD-Th shows capability to increase the PCEs of polymer solar cells (PSCs) with a non-fullerene acceptor.
Palavras-chave
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Polímeros
/
Energia Solar
/
Tiofenos
Idioma:
En
Revista:
Macromol Rapid Commun
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
China