Liquid-Phase Synthesis of Boron Isocyanates: Precursors to Boron Nanoparticles.
Angew Chem Int Ed Engl
; 57(45): 14888-14890, 2018 Nov 05.
Article
em En
| MEDLINE
| ID: mdl-30218475
ABSTRACT
The practical application of boron isocyanates has been hindered by their extremely high sensitivity and reactivity toward air and moisture. A convenient synthetic method in a suitable liquid media is reported for practical utilization of boron isocyanates. According to NMR studies, the in situ generated boron isocyanates can be stored for at least one month under an inert atmosphere at -20 °C without noticeable decomposition. The boron tri(isocyanate) (B(NCO)3 ) was converted into boron nanoparticles by reduction with hydrogen under mild reaction conditions.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
Macau