Norepinephrine-functionalised nanoflower-like organic silica as a new adsorbent for effective Pb(II) removal from aqueous solutions.

ABSTRACT

In order to remove Pb(II) ions efficiently from aqueous solutions, a new effective adsorbent of norepinephrine-functionalised nanoflower-like organic silica (NE-NFOS) was synthesised by a biomimetic method. Biomimetic functionalization with norepinephrine has the advantages of environment-friendly and easy operation. Characterization of the NE-NFOS using scanning electron microscopy, transmission electron microscopy, Brunauer-Emmett-Teller method, and Fourier-transform infrared spectroscopy revealed that the NFOS was modified successfully by norepinephrine. Furthermore, the influences of different parameters including adsorption kinetics, solution pH, adsorption isotherms, concentrations of Na+, K+, Ca2+, and Mg2+, desorption and reusability were studied. The adsorption experiments showed that the capacity of NE-NFOS to adsorb Pb(II) ions improved greatly after functionalisation and adsorption equilibrium was attained within 90 min at a pH of 6.0. The Na+, K+, Ca2+, and Mg2+ concentrations had little influence on the adsorption, and after recycling for five times, the Pb(II) ion removal efficiency of the adsorbent was more than 79% of its initial value. Thus, it was demonstrated that the NE-NFOS with excellent adsorption performance could be a suitable adsorbent for Pb(II) ions removal in practical applications.