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Multi-scale ordering in highly stretchable polymer semiconducting films.
Xu, Jie; Wu, Hung-Chin; Zhu, Chenxin; Ehrlich, Anatol; Shaw, Leo; Nikolka, Mark; Wang, Sihong; Molina-Lopez, Francisco; Gu, Xiaodan; Luo, Shaochuan; Zhou, Dongshan; Kim, Yun-Hi; Wang, Ging-Ji Nathan; Gu, Kevin; Feig, Vivian Rachel; Chen, Shucheng; Kim, Yeongin; Katsumata, Toru; Zheng, Yu-Qing; Yan, He; Chung, Jong Won; Lopez, Jeffrey; Murmann, Boris; Bao, Zhenan.
Afiliação
  • Xu J; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Wu HC; Nanoscience and Technology Division, Argonne National Laboratory, Lemont, IL, USA.
  • Zhu C; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Ehrlich A; Department of Electrical Engineering, Stanford University, Stanford, CA, USA.
  • Shaw L; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Nikolka M; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Wang S; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Molina-Lopez F; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Gu X; Institute for Molecular Engineering, University of Chicago, Chicago, IL, USA.
  • Luo S; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Zhou D; Department of Materials Engineering, KU Leuven, Belgium.
  • Kim YH; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Wang GN; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Gu K; School of Polymer Science and Engineering, University of Southern Mississippi, Hattiesburg, MS, USA.
  • Feig VR; Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, China.
  • Chen S; Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, China.
  • Kim Y; Department of Chemistry and RINS, Gyeongsang National University, Jinju, South Korea.
  • Katsumata T; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Zheng YQ; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Yan H; Department of Materials Science and Engineering, Stanford University, Stanford, CA, USA.
  • Chung JW; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Lopez J; Department of Electrical Engineering, Stanford University, Stanford, CA, USA.
  • Murmann B; Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Bao Z; Corporate Research and Development, Performance Materials Technology Center, Asahi Kasei Corporation, Fuji, Shizuoka, Japan.
Nat Mater ; 18(6): 594-601, 2019 06.
Article em En | MEDLINE | ID: mdl-30988452
Stretchable semiconducting polymers have been developed as a key component to enable skin-like wearable electronics, but their electrical performance must be improved to enable more advanced functionalities. Here, we report a solution processing approach that can achieve multi-scale ordering and alignment of conjugated polymers in stretchable semiconductors to substantially improve their charge carrier mobility. Using solution shearing with a patterned microtrench coating blade, macroscale alignment of conjugated-polymer nanostructures was achieved along the charge transport direction. In conjunction, the nanoscale spatial confinement aligns chain conformation and promotes short-range π-π ordering, substantially reducing the energetic barrier for charge carrier transport. As a result, the mobilities of stretchable conjugated-polymer films have been enhanced up to threefold and maintained under a strain up to 100%. This method may also serve as the basis for large-area manufacturing of stretchable semiconducting films, as demonstrated by the roll-to-roll coating of metre-scale films.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Nat Mater Assunto da revista: CIENCIA / QUIMICA Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Estados Unidos
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Nat Mater Assunto da revista: CIENCIA / QUIMICA Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Estados Unidos