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Synthesis, Self-Assembly and Characterization of Tandem Triblock BPOSS-PDI-X Shape Amphiphiles.
Shao, Yu; Chen, Jia; Ren, Xiang-Kui; Zhang, Xinlin; Yin, Guang-Zhong; Li, Xiaopeng; Wang, Jing; Wesdemiotis, Chrys; Zhang, Wen-Bin; Yang, Shuguang; Sun, Bin; Zhu, Meifang.
Afiliação
  • Shao Y; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China. boukephalas@outlook.com.
  • Chen J; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China. 2170464@mail.dhu.edu.cn.
  • Ren XK; School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China. renxiangkui@tju.edu.cn.
  • Zhang X; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China. zhangxl2015@sjtu.edu.cn.
  • Yin GZ; Department of Chemistry, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. gzh_yin@126.com.
  • Li X; Department of Chemistry, University of South Florida, 4202 East Fowler Ave, Tampa, FL 33620, USA. xiaopengli1@usf.edu.
  • Wang J; South China Advanced Institute of Soft Matter Science and Technology, South China University of Technology, Guangzhou 510640, China. wangj81@scut.edu.cn.
  • Wesdemiotis C; Department of Chemistry, The University of Akron, Akron, OH 44325, USA. wesdemiotis@uakron.edu.
  • Zhang WB; Department of Chemistry, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. wenbin@pku.edu.cn.
  • Yang S; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China. shgyang@dhu.edu.cn.
  • Sun B; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China. sunbin@dhu.edu.cn.
  • Zhu M; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China. zmf@dhu.edu.cn.
Molecules ; 24(11)2019 Jun 04.
Article em En | MEDLINE | ID: mdl-31167411
ABSTRACT
In this article, we report the facile synthesis, self-assembly, and characterization of shape amphiphiles (BPOSS-PDI-X) based on isobutyl-functionalized polyhedral oligomeric silsesquioxane (BPOSS), perylene tetracarboxylic diimide (PDI), and (60)fullerene (C60) moieties. Firstly, an asymmetrically functionalized diblock shape amphiphile precursor (BPOSS-PDI-OH) was obtained through the one-pot reaction between perylene-3,4,9,10-tetracarboxylic dianhydride and two different amines, namely BPOSS-NH2 and 3-amino-1-propanol. It was further conjugated with C60-COOH to give a tri-block shape amphiphile (BPOSS-PDI-C60). Their chemical structures were thoroughly characterized by NMR, IR and MALDI-TOF MS spectrometry. In order to gain insights on the structure-property relationship, their self-assembly in gas phase, in solution, and in solid state were characterized using traveling wave ion mobility mass spectrometry (TWIM-MS), UV/Vis absorption, fluorescence emission spectrophotometer, and transmission electron microscopy, respectively. It was found that BPOSS-PDI-OH formed more complicated dimers than BPOSS-PDI-C60. Both samples showed unique aggregation behaviors in solution with increasing concentration, which could be attributed neither to H- nor to J-type and might be related to the discrete dimers. While BPOSS-PDI-C60 could hardly crystalize into ordered structures, BPOSS-PDI-OH could form nanobelt-shaped single crystals, which may hold potential applications in microelectronics.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Perileno / Tensoativos / Fulerenos / Imidas Idioma: En Revista: Molecules Assunto da revista: BIOLOGIA Ano de publicação: 2019 Tipo de documento: Article País de afiliação: China
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Perileno / Tensoativos / Fulerenos / Imidas Idioma: En Revista: Molecules Assunto da revista: BIOLOGIA Ano de publicação: 2019 Tipo de documento: Article País de afiliação: China