Calcium stannyl formation by organostannane dehydrogenation.

Morris, Louis J; Hill, Michael S; Manners, Ian; McMullin, Claire L; Mahon, Mary F; Rajabi, Nasir A

Morris, Louis J; Hill, Michael S; Manners, Ian; McMullin, Claire L; Mahon, Mary F; Rajabi, Nasir A.

Afiliação

Morris LJ; Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK. msh27@bath.ac.uk.
Hill MS; Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK. msh27@bath.ac.uk.
Manners I; Department of Chemistry, University of Victoria, Victoria, BC V8P 5C2, Canada.
McMullin CL; Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK. msh27@bath.ac.uk.
Mahon MF; Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK. msh27@bath.ac.uk.
Rajabi NA; Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK. msh27@bath.ac.uk.

Chem Commun (Camb) ; 55(86): 12964-12967, 2019 Oct 24.

Article em En | MEDLINE | ID: mdl-31603152

RESUMO

Reaction of the dimeric calcium hydride, [(BDI)CaH]2 (1), with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-µ2-H-(SnPh3)Ca(BDI)] (3) and [(BDI)Ca(SnPh3)]2 (4) alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2019 Tipo de documento: Article

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