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Crown ether-appended calix[2]triazolium[2]arene as a macrocyclic receptor for the recognition of the H2PO4- anion.
Cho, Jihee; Verwilst, Peter; Kang, Minjung; Pan, Jia-Lin; Sharma, Amit; Hong, Chang Seop; Kim, Jong Seung; Kim, Sanghee.
Afiliação
  • Cho J; College of Pharmacy, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Korea. pennkim@snu.ac.kr.
  • Verwilst P; Department of Chemistry, Korea University, Seoul 02841, Korea. jongskim@korea.ac.kr cshong@korea.ac.kr.
  • Kang M; Department of Chemistry, Korea University, Seoul 02841, Korea. jongskim@korea.ac.kr cshong@korea.ac.kr.
  • Pan JL; Department of Chemistry, Korea University, Seoul 02841, Korea. jongskim@korea.ac.kr cshong@korea.ac.kr.
  • Sharma A; Department of Chemistry, Korea University, Seoul 02841, Korea. jongskim@korea.ac.kr cshong@korea.ac.kr.
  • Hong CS; Department of Chemistry, Korea University, Seoul 02841, Korea. jongskim@korea.ac.kr cshong@korea.ac.kr.
  • Kim JS; Department of Chemistry, Korea University, Seoul 02841, Korea. jongskim@korea.ac.kr cshong@korea.ac.kr.
  • Kim S; College of Pharmacy, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Korea. pennkim@snu.ac.kr.
Chem Commun (Camb) ; 56(7): 1038-1041, 2020 Jan 21.
Article em En | MEDLINE | ID: mdl-31850459
ABSTRACT
A crown ether-appended calix[2]triazolium[2]arene, which exhibits excellent selectivity for H2PO4- compared to other anions, has been designed and synthesized. The selectivity of the prepared receptor for H2PO4- is caused by the stabilization of H2PO4- by the neighboring triazolium hydrogen bond donors and crown ether hydrogen bond acceptors.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2020 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2020 Tipo de documento: Article