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Self-Assembly of a Ti4(embonate)6 Cage toward Silver.
Chen, Guang-Hui; Li, De-Jing; He, Yan-Ping; Zhang, Shu-Hua; Liang, Fu-Pei; Zhang, Jian.
Afiliação
  • Chen GH; College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, P. R. China.
  • Li DJ; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China.
  • He YP; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China.
  • Zhang SH; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China.
  • Liang FP; College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, P. R. China.
  • Zhang J; College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, P. R. China.
Inorg Chem ; 59(20): 14861-14865, 2020 Oct 19.
Article em En | MEDLINE | ID: mdl-33026801
ABSTRACT
Herein we report a variety of supramolecular architectures that are self-assembled by the highly charged anionic Ti4L6 (L = embonate) cages and noble-metal Ag+ ions in the presence of the different ligands, including six Ti4L6-Ag(PPh3) cages in whose structures the Ti4L6 cage catches various in situ formed [Ag(PPh3)]+ moieties by a coordination bond and one cocrystal superstructure of a Ti4L6 cage with an in situ generated [Ag2(Ph2P(CH2)5PPh2)3]2+ cage via supramolecular interactions. In addition, the third-order nonlinear-optical properties of these compounds are investigated in detail.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2020 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2020 Tipo de documento: Article