Thermally-driven gold@poly(N-isopropylacrylamide) core-shell nanotransporters for molecular extraction.
J Colloid Interface Sci
; 584: 789-794, 2021 Feb 15.
Article
em En
| MEDLINE
| ID: mdl-33268066
ABSTRACT
HYPOTHESIS:
Molecular extraction efficiency can be boosted with the assistance of nanoparticles (NPs). It is based on adsorption of the extractants in one phase and desorption in another phase, which requires a reversible phase transfer of the NPs. EXPERIMENTS We synthesized the gold@poly(N-isopropylacryamide) (Au@PNIPAM) NPs via an interfacial self-assembly method enhanced by post-polymerization. We adopted Rhodamine 6G (R6G) as the model molecule for the extraction test. In comparison, UV-Vis extinction spectra were recorded to monitor the extraction processes with or without the Au@PNIPAM NPs. We further analyzed theoretically with thermodynamics and first-principle calculations.FINDINGS:
The hybrid Au@PNIPAM NPs show a reversible phase transfer between the interface and chloroform phases. The Au NPs assisted extraction efficiency of R6G shows 5 times higher than that without Au NPs. The thermodynamic analysis of the nanotransportation system agrees well with the ab initio density functional theory calculations. This nanoparticle-assisted molecular transportation modifies the extraction kinetics significantly, which will provide further implications for biphasic catalysis, pollutant treatment and drug delivery.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Tipo de estudo:
Prognostic_studies
Idioma:
En
Revista:
J Colloid Interface Sci
Ano de publicação:
2021
Tipo de documento:
Article