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Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3.
He, Xiaolong; Zhang, Xinyuan; Ji, Bifa; Yao, Wenjiao; Lightfoot, Philip; Tang, Yongbing.
Afiliação
  • He X; Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China. wj.yao@siat.ac.cn tangyb@siat.ac.cn and Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215123, China.
  • Zhang X; Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystals, Tianjin University of Technology, Tianjin 300384, China.
  • Ji B; Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China. wj.yao@siat.ac.cn tangyb@siat.ac.cn and Shenzhen Institute of Advanced Technology, University of Chinese Academy of Sciences, Shenzhen 518055, China.
  • Yao W; Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China. wj.yao@siat.ac.cn tangyb@siat.ac.cn.
  • Lightfoot P; School of Chemistry and EaStChem, University of St Andrews, St Andrews, Fife KY16 9ST, UK. pl@st-andrews.ac.uk.
  • Tang Y; Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China. wj.yao@siat.ac.cn tangyb@siat.ac.cn and Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215123, China and Shenzhen Inst
Chem Commun (Camb) ; 57(20): 2567-2570, 2021 Mar 09.
Article em En | MEDLINE | ID: mdl-33587732
ABSTRACT
In the title compound, the oxalate ligand simultaneously bridges both Mn-centred and Na-centred octahedra to produce a unique 'doubly-interpenetrated' perovskite-like lattice with an unconventional octahedral tilt system. In turn, the coordination requirements of the oxalate ligand lead to a rare 'twisted' conformation.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: China
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: China