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Asymmetric Reduction of Aromatic α-Dehydroamino Acid Esters with Water as Hydrogen Source.
Dai, Yuze; Chen, Jingchao; Wang, Zheting; Wang, Ting; Wang, Lin; Yang, Yong; Qiao, Xingfang; Fan, Baomin.
Afiliação
  • Dai Y; Key Laboratory of Chemistry in Ethnic Medicinal Resources (Yunnan Minzu University), State Ethnic Affairs Commission and Ministry of Education, Yunnan Minzu University, Kunming 650504, Yunnan, China.
  • Chen J; Key Laboratory of Chemistry in Ethnic Medicinal Resources (Yunnan Minzu University), State Ethnic Affairs Commission and Ministry of Education, Yunnan Minzu University, Kunming 650504, Yunnan, China.
  • Wang Z; Key Laboratory of Chemistry in Ethnic Medicinal Resources (Yunnan Minzu University), State Ethnic Affairs Commission and Ministry of Education, Yunnan Minzu University, Kunming 650504, Yunnan, China.
  • Wang T; Key Laboratory of Chemistry in Ethnic Medicinal Resources (Yunnan Minzu University), State Ethnic Affairs Commission and Ministry of Education, Yunnan Minzu University, Kunming 650504, Yunnan, China.
  • Wang L; Key Laboratory of Chemistry in Ethnic Medicinal Resources (Yunnan Minzu University), State Ethnic Affairs Commission and Ministry of Education, Yunnan Minzu University, Kunming 650504, Yunnan, China.
  • Yang Y; Chongqing Key Laboratory of Traditional Chinese Medicine Health, Chongqing Accademy of Chinese Materia Medica, Chongqing 400065, China.
  • Qiao X; Chongqing Key Laboratory of Traditional Chinese Medicine Health, Chongqing Accademy of Chinese Materia Medica, Chongqing 400065, China.
  • Fan B; Key Laboratory of Chemistry in Ethnic Medicinal Resources (Yunnan Minzu University), State Ethnic Affairs Commission and Ministry of Education, Yunnan Minzu University, Kunming 650504, Yunnan, China.
J Org Chem ; 86(10): 7141-7147, 2021 05 21.
Article em En | MEDLINE | ID: mdl-33966384
ABSTRACT
The asymmetric reduction of aromatic α-dehydroamino acid esters with water as the hydrogen source was developed by a Rh/Cu co-catalytic system. The reaction tolerates various functional groups, providing a valuable synthetic tool to access chiral α-amino acid esters readily. Moreover, the present methodology also was applied in the cost-effective and easy to handle preparation of chiral deuterated α-amino esters by using D2O.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Água / Ésteres Idioma: En Revista: J Org Chem Ano de publicação: 2021 Tipo de documento: Article País de afiliação: China
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Água / Ésteres Idioma: En Revista: J Org Chem Ano de publicação: 2021 Tipo de documento: Article País de afiliação: China