Heterogeneous alkane dehydrogenation catalysts investigated via a surface organometallic chemistry approach.
Chem Soc Rev
; 50(9): 5806-5822, 2021 May 11.
Article
em En
| MEDLINE
| ID: mdl-33972978
ABSTRACT
The selective conversion of light alkanes (C2-C6 saturated hydrocarbons) to the corresponding alkene is an appealing strategy for the petrochemical industry in view of the availability of these feedstocks, in particular with the emergence of Shale gas. Here, we present a review of model dehydrogenation catalysts of light alkanes prepared via surface organometallic chemistry (SOMC). A specific focus of this review is the use of molecular strategies for the deconvolution of complex heterogeneous materials that are proficient in enabling dehydrogenation reactions. The challenges associated with the proposed reactions are highlighted, as well as overriding themes that can be ascertained from the systematic study of these challenging reactions using model SOMC catalysts.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Soc Rev
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
Suíça