Optical Anisotropy and Phase Transitions in Lead Halide Perovskites.
J Phys Chem Lett
; 12(20): 5016-5022, 2021 May 27.
Article
em En
| MEDLINE
| ID: mdl-34018751
ABSTRACT
Optical anisotropy originates from crystalline structures with low symmetry and governs the polarization-dependent light propagation. Optical anisotropy is particularly important to lead halide perovskites that have been under intense investigation for optoelectronic and photonic applications, as this group of materials possesses rich structural phases that deviate from the high-symmetry cubic phase. Here we apply 2D optical Kerr effect spectroscopy to quantify the optical anisotropy in single-crystal methylammonium lead bromide (MAPbBr3). We determine the strong photon energy dependence of optical anisotropy near the band gap and show the dramatic change in optical anisotropy across phase transitions. We correlate the optical anisotropy with the structural anisotropy and demonstrate the tuning of optical anisotropy by alloyed CsxMA1-xPbBr3 perovskite crystals.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Phys Chem Lett
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
Estados Unidos