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Thermally induced transformation of a Cu4I4-based cluster to a Cu2I2-based cluster under mild conditions.
Jiang, Cheng-Gang; Yuan, Yan-Fang; Meng, Xiao-Yu; Zhou, Ke-Ke; Zhuang, Gui-Lin; Li, Bao; Zhang, Tianle.
Afiliação
  • Jiang CG; Key laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, PR China. libao@hust.edu.cn tlzhang@hust.edu.cn.
  • Yuan YF; Key laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, PR China. libao@hust.edu.cn tlzhang@hust.edu.cn.
  • Meng XY; Key laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, PR China. libao@hust.edu.cn tlzhang@hust.edu.cn.
  • Zhou KK; Key laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, PR China. libao@hust.edu.cn tlzhang@hust.edu.cn.
  • Zhuang GL; Institute of Industrial Catalysis, College of Chemical Engineering Zhejiang University of Technology, Zhejiang 310023, People's Republic of China.
  • Li B; Key laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, PR China. libao@hust.edu.cn tlzhang@hust.edu.cn.
  • Zhang T; Key laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, PR China. libao@hust.edu.cn tlzhang@hust.edu.cn.
Dalton Trans ; 50(26): 9016-9020, 2021 Jul 06.
Article em En | MEDLINE | ID: mdl-34152339
ABSTRACT
A reaction of 6,6'-bis((benzylthio)methyl)-2,2'-bipyridine (L) with CuI at room temperature led to one Cu4I4-based cluster, which could be thermally transformed to a Cu2I2-based one under mild conditions due to the formation of a Cu-S bond. Along with the structural transformation, remarkable changes in the color and luminescence have been triggered.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article