Tandem elimination-oxidation of tertiary benzylic alcohols with an oxoammonium salt.

Meador, Rowan I L; Anderson, Robert E; Chisholm, John D

Meador, Rowan I L; Anderson, Robert E; Chisholm, John D.

Afiliação

Meador RIL; Department of Chemistry, Syracuse University, 1-014 Center for Science and Technology, Syracuse, NY 13244, USA. jdchisho@syr.edu.
Anderson RE; Department of Chemistry, Syracuse University, 1-014 Center for Science and Technology, Syracuse, NY 13244, USA. jdchisho@syr.edu.
Chisholm JD; Department of Chemistry, Syracuse University, 1-014 Center for Science and Technology, Syracuse, NY 13244, USA. jdchisho@syr.edu.

Org Biomol Chem ; 19(28): 6233-6236, 2021 07 21.

Article em En | MEDLINE | ID: mdl-34231623

ABSTRACT

ABSTRACT

Tertiary benzylic alcohols react with oxoammonium salts, undergoing a tandem elimination/allylic oxidation to provide an allylic ether product in a single step. This mode of reactivity provides a rapid entry into allylic ethers from certain benzylic tertiary alcohols. The allylic ether may be cleaved under reductive conditions to reveal the allylic alcohol.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Estados Unidos

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