Direct Electrochemical Selenylation/Cyclization of Alkenes: Access to Functionalized Benzheterocycles.
J Org Chem
; 86(22): 16045-16058, 2021 11 19.
Article
em En
| MEDLINE
| ID: mdl-34328728
A catalyst-free, environmentally friendly, and efficient electrochemical selenylation/cyclization of alkenes has been developed with moderate to excellent yields. This selenylated transformation proceeds smoothly and tolerates a wide range of synthetically useful groups to deliver diverse functionalized benzheterocycles, including iminoisobenzofuran, lactones, oxindoles, and quinolinones. Moreover, the present synthetic route could also be readily scaled up to gram quantity with convenient operation in an undivided cell.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Alcenos
/
Indóis
Idioma:
En
Revista:
J Org Chem
Ano de publicação:
2021
Tipo de documento:
Article