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A new metal-organic framework based on rare [Zn4F4] cores for efficient separation of C2H2.
Shi, Wen-Juan; Li, Yong-Zhi; Chen, Jing; Su, Run-Han; Hou, Lei; Wang, Yao-Yu; Zhu, Zhonghua.
Afiliação
  • Shi WJ; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China. yzli1120@foxmail.com.
  • Li YZ; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China. yzli1120@foxmail.com.
  • Chen J; School of Materials and Physics, China University of Mining & Technology, Xuzhou 221116, P. R. China.
  • Su RH; Shaanxi Yanchang Petroleum (Group) Co., Ltd, Xi'an 710000, P. R. China.
  • Hou L; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China. yzli1120@foxmail.com.
  • Wang YY; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China. yzli1120@foxmail.com.
  • Zhu Z; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China. yzli1120@foxmail.com.
Chem Commun (Camb) ; 57(95): 12788-12791, 2021 Nov 30.
Article em En | MEDLINE | ID: mdl-34782899
Assembly via 1,4-benzenedicarboxylate linkers and Zn2+ ions afforded an MOF containing rare [Zn4F4] cubane core, showing excellent separation for C2H2-CO2 and C2H2-CH4 mixtures. Dynamic breakthrough experiments and grand canonical Monte Carlo calculations were carried out to confirm the feasibility of the MOF for the separation application of C2H2.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article