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Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts.
Sallio, Romain; Payard, Pierre-Adrien; Pakulski, Pawel; Diachenko, Iryna; Fabre, Indira; Berteina-Raboin, Sabine; Colas, Cyril; Ciofini, Ilaria; Grimaud, Laurence; Gillaizeau, Isabelle.
Afiliação
  • Sallio R; Institute of Organic and Analytical Chemistry, ICOA UMR 7311 CNRS, Université d'Orléans rue de Chartres 45100 Orléans France Isabelle.gillaizeau@univ-orleans.fr.
  • Payard PA; Laboratoire des Biomolécules, LBM, Département de chimie, École normale supérieure, PSL University, Sorbonne Université, CNRS 75005 Paris France laurence.grimaud@ens.psl.eu.
  • Pakulski P; Institute of Organic and Analytical Chemistry, ICOA UMR 7311 CNRS, Université d'Orléans rue de Chartres 45100 Orléans France Isabelle.gillaizeau@univ-orleans.fr.
  • Diachenko I; Institute of Organic and Analytical Chemistry, ICOA UMR 7311 CNRS, Université d'Orléans rue de Chartres 45100 Orléans France Isabelle.gillaizeau@univ-orleans.fr.
  • Fabre I; Laboratoire des Biomolécules, LBM, Département de chimie, École normale supérieure, PSL University, Sorbonne Université, CNRS 75005 Paris France laurence.grimaud@ens.psl.eu.
  • Berteina-Raboin S; Institute of Organic and Analytical Chemistry, ICOA UMR 7311 CNRS, Université d'Orléans rue de Chartres 45100 Orléans France Isabelle.gillaizeau@univ-orleans.fr.
  • Colas C; Institute of Organic and Analytical Chemistry, ICOA UMR 7311 CNRS, Université d'Orléans rue de Chartres 45100 Orléans France Isabelle.gillaizeau@univ-orleans.fr.
  • Ciofini I; Institute of Chemistry for Health and Life Sciences, I-CLeHS, Chimie ParisTech, PSL University, CNRS 75005 Paris France.
  • Grimaud L; Laboratoire des Biomolécules, LBM, Département de chimie, École normale supérieure, PSL University, Sorbonne Université, CNRS 75005 Paris France laurence.grimaud@ens.psl.eu.
  • Gillaizeau I; Institute of Organic and Analytical Chemistry, ICOA UMR 7311 CNRS, Université d'Orléans rue de Chartres 45100 Orléans France Isabelle.gillaizeau@univ-orleans.fr.
RSC Adv ; 11(26): 15885-15889, 2021 Apr 26.
Article em En | MEDLINE | ID: mdl-35481165
This work reports a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles using eco-friendly diaryliodonium salts and leading to N-arylacetamides. The method features high efficiency, broad substrate scope and good functional group tolerance.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: RSC Adv Ano de publicação: 2021 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: RSC Adv Ano de publicação: 2021 Tipo de documento: Article