Conversion of Polypropylene Waste into Value-Added Products: A Greener Approach.

ABSTRACT

Plastic has made our lives comfortable as a result of its widespread use in today's world due to its low cost, longevity, adaptability, light weight and hardness; however, at the same time, it has made our lives miserable due to its non-biodegradable nature, which has resulted in environmental pollution. Therefore, the focus of this research work was on an environmentally friendly process. This research work investigated the decomposition of polypropylene waste using florisil as the catalyst in a salt bath over a temperature range of 350-430 °C. A maximum oil yield of 57.41% was recovered at 410 °C and a 40 min reaction time. The oil collected from the decomposition of polypropylene waste was examined using gas chromatography-mass spectrometry (GC-MS). The kinetic parameters of the reaction process were calculated from thermogravimetric data at temperature program rates of 3, 12, 20 and 30 °C·min-1 using the Ozawa-Flynn-Wall (OFW) and Kissinger-Akahira-Sunnose (KAS) equations. The activation energy (Ea) and pre-exponential factor (A) for the thermo-catalytic degradation of polypropylene waste were observed in the range of 102.74-173.08 kJ·mol-1 and 7.1 × 108-9.3 × 1011 min-1 for the OFW method and 99.77-166.28 kJ·mol-1 and 1.1 × 108-5.3 × 1011 min-1 for the KAS method at a percent conversion (α) of 0.1 to 0.9, respectively. Moreover, the fuel properties of the oil were assessed and matched with the ASTM values of diesel, gasoline and kerosene oil. The oil was found to have a close resemblance to the commercial fuel. Therefore, it was concluded that utilizing florisil as the catalyst for the decomposition of waste polypropylene not only lowered the activation energy of the pyrolysis reaction but also upgraded the quantity and quality of the oil.