Visible-Light Photoredox-Catalyzed Synthesis of <i>trans</i>-Oxiranes via Decarboxylative Stereospecific Epoxidation of <i>trans</i>-Cinnamic Acids by Aryldiazonium Salts.

Chand, Shiv; Sharma, Anup Kumar; Pandey, Anand Kumar; Singh, Krishna Nand

Visible-Light Photoredox-Catalyzed Synthesis of trans-Oxiranes via Decarboxylative Stereospecific Epoxidation of trans-Cinnamic Acids by Aryldiazonium Salts.

Chand, Shiv; Sharma, Anup Kumar; Pandey, Anand Kumar; Singh, Krishna Nand.

Afiliação

Chand S; Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi 221005, India.
Sharma AK; Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi 221005, India.
Pandey AK; Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi 221005, India.
Singh KN; Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi 221005, India.

Org Lett ; 24(35): 6423-6427, 2022 09 09.

Article em En | MEDLINE | ID: mdl-36030413

RESUMO

An efficient visible-light-induced synthesis of trans-oxiranes has been accomplished via decarboxylative stereospecific epoxidation of trans-cinnamic acids by aryldiazonium salts using CuCl, eosin Y, TBHP, and DBU. The reaction is facile, straightforward, and endowed with good functional group tolerability and a good substrate scope.

Assuntos

Compostos de Epóxi; Sais; Catálise; Luz; Estrutura Molecular

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Sais / Compostos de Epóxi Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Índia

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