A sustainable approach for selective recovery of lithium from cathode materials of spent lithium-ion batteries by induced phase transition.
Waste Manag
; 156: 247-254, 2023 Feb 01.
Article
em En
| MEDLINE
| ID: mdl-36502638
ABSTRACT
Recycling of spent lithium-ion batteries (LIBs) has attracted widespread attention because of their dual attributes to environmental protection and resource conservation. Utilization of strong corrosive acids is currently the preferred way to recover valuable metals from spent LIBs, but the extensive use of chemical reagents can pose serious environmental risks. Herein, this research proposes a green process for selective recovery of lithium using the material of spent LIBs itself without adding exogenous reagents, mechanochemistry induced phase transition. The leaching efficiency of Li can reach 94% by employing the copper foil separated from spent LIBs as the co-grinding additive during the mechanochemical reaction process. Then, the high value LiOH·H2O can be prepared through direct evaporation and crystallization without adding any precipitant. Meanwhile, cobalt is almost remained in the leaching residue which can be recovered through a step-by-step separation process. XRD, XPS, and SEM-EDS characterizations show that LiCoO2 and copper foil are transformed into the soluble Li2O, and insoluble CuO and CoO under the mechanical force. Finally, the soluble Li2O is dissolved in water to prepare the LiOH solution, and the insoluble CuO and CoO are transformed into Cu2O and Co(OH)2. On the basis of the experimental investigation, it is proven that the proposed process is suitable for selectively recovering Li from all types of cathode materials without generating salty wastewater or introducing chemical reagents. Thus, the proposed approach can ensure the efficient recovery of valuable metals from spent LIBs while avoiding the potential threat to the environment and human health.
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Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Cobre
/
Lítio
Limite:
Humans
Idioma:
En
Revista:
Waste Manag
Assunto da revista:
SAUDE AMBIENTAL
/
TOXICOLOGIA
Ano de publicação:
2023
Tipo de documento:
Article