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Highly Stable Triangular Single-Layer 2D Assemblies: Synthesis and Their Stimuli-Responsive Elastic and Anisotropic Curling.
Hao, Yajiao; Yu, Lin; Miyazawa, Keisuke; Zhang, Shengrui; Liu, Mo; Yu, Zhongqi; Liu, Jun; Yu, Yang; Li, Song; Xu, Shujue; Fukuma, Takeshi; Xiao-An Zhang, Sean; Li, Minjie.
Afiliação
  • Hao Y; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.
  • Yu L; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.
  • Miyazawa K; Faculty of Frontier Engineering, Kanazawa University Kakuma-machi, 920-1192, Kanazawa, Japan.
  • Zhang S; Nano Life Science Institute (WPI-NanoLSI), Kanazawa University, Kakuma-machi, 920-1192, Kanazawa, Japan.
  • Liu M; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.
  • Yu Z; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.
  • Liu J; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.
  • Yu Y; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.
  • Li S; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.
  • Xu S; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.
  • Fukuma T; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.
  • Xiao-An Zhang S; Faculty of Frontier Engineering, Kanazawa University Kakuma-machi, 920-1192, Kanazawa, Japan.
  • Li M; Nano Life Science Institute (WPI-NanoLSI), Kanazawa University, Kakuma-machi, 920-1192, Kanazawa, Japan.
Angew Chem Int Ed Engl ; 62(22): e202302365, 2023 May 22.
Article em En | MEDLINE | ID: mdl-36973174
ABSTRACT
Synthesis of highly stable two-dimensional single-layer assemblies (SLAs) is a key challenge in supramolecular science, especially those with long-range molecular order and well-defined morphology. Here, thin (thickness <2 nm) triangular AuI -thiolate SLAs with high thermo-, solvato- and mechano- stability have been synthesized via a double-ligand co-assembly strategy. Furthermore, the SLAs show assembly-level elastic and anisotropic deformation responses to external stimuli as a result of the long-range anisotropic molecular packing, which provides SLAs with new application potentials in bio-mimic nanomechanics.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2023 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2023 Tipo de documento: Article