NMR Surface Relaxivity in a Time-Dependent Porous System.
Phys Rev Lett
; 130(12): 126204, 2023 Mar 24.
Article
em En
| MEDLINE
| ID: mdl-37027882
ABSTRACT
We demonstrate an unexpected decay-recovery behavior in the time-dependent ^{1}H NMR relaxation times of water confined within a hydrating porous material. Our observations are rationalized by considering the combined effects of decreasing material pore size and evolving interfacial chemistry, which facilitate a transition between surface-limited and diffusion-limited relaxation regimes. Such behavior necessitates the realization of temporally evolving surface relaxivity, highlighting potential caveats in the classical interpretation of NMR relaxation data obtained from complex porous systems.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Phys Rev Lett
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
Austrália