Photoelectrocatalyzed undirected C-H trifluoromethylation of arenes: catalyst evaluation and scope.

During the last few years, photoelectrocatalysis has evolved as an increasingly viable tool for molecular synthesis. Despite several recent reports on the undirected C-H functionalization of arenes, thus far, a detailed comparison of different catalysts is still missing. To address this, more than a dozen different mediators were employed in the trifluoromethylation of (hetero-)arenes to compare them in their efficacies.